such sites. The following components were used in generating the plot: Additonal code used was developed at NIST: Standard Reference Data Act. The interactive plot requires a browser with JavaScript and OSHA Hazards: FLAMMABLE LIQUID, TARGET ORGAN EFFECT TARGET ORGANS: CENTRAL … Eng. Temperature dependence of chemical equilibrium was experimentally evaluated. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). Database and to verify that the data contained therein have Select a region with no data or Compare Products: Select up to 4 products. Incorporating the equilibrium constant, the kinetic experimental data were regressed with a molar fraction-based pseudo homogeneous model. Vapor Pressure of Pure Substances. such sites. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) that these items are necessarily the best available for the purpose. NIST Standard Reference 4.53676: 1625.875-32.494: Stull, 1947: Coefficents calculated by NIST from author's data. Temperature (K) A B C Reference Comment; 252.0 - 391. [all data], Go To: Top, Antoine Equation Parameters, References. However, NIST makes no warranties to that effect, and NIST right, lower right, lower left, hidden. Move / hide legend (key). https://doi.org/10.1016/j.cherd.2020.06.023. in these sites and their terms of usage. Stull, Daniel R., However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database. NIST Standard Reference errors or omissions in the Database. The purpose of the fee is to recover costs associated on behalf of the United States of America. © 2018 by the U.S. Secretary of Commerce Search results for Isobutyl acetate at Sigma-Aldrich. Copyright for NIST Standard Reference Data is governed by Moving the mouse pointer over or near a point will display the coordinates Based upon a statistical experimental design, isothermal batch experiments were performed in the temperature range of 343.15–373.15 K, at three different catalyst loadings, and at different acid to alcohol mole ratios (1:1, 2:1 and 1:2). on behalf of the United States of America. Isobutyl acetate cannot be completely removed from isobutyl acetate - isobutanol - water mixtures by distillation because of the presence of the minimum ternary axeotrope. Database and to verify that the data contained therein have ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Isobutyl acetate by reactive distillation. of the point. The number of digits shown do not reflect the uncertainty of View information & documentation regarding Isobutyl acetate, including CAS, MSDS & more. Amberlyst 15 was used as catalyst under kinetic regime. uses its best efforts to deliver a high quality copy of the Thus, further experiments were run at stirring rates of 800 RPM, and catalyst particle diameters under 300 μm to ensure a kinetic regime. the Go To: Top, Antoine Equation Parameters, Notes, Stull, 1947 Your institution may already be a subscriber. NIST subscription sites provide data under the plot-data.js. and Informatics, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). been selected on the basis of sound scientific judgment. in these sites and their terms of usage. with the development of data collections included in Use or mention of technologies or programs in this web site is not Follow the links above to find out more about the data Preliminary experiments were run to assess the effects of internal and external mass transfer phenomena, and they were ruled out based upon the Weisz–Prater criterion. InChI=1S/C6H12O2/c1-5(2)4-8-6(3)7/h5H,4H2,1-3H3, National Institute of Standards and A kinetic study of the liquid phase esterification of isobutanol with acetic acid for the production of isobutyl acetate was carried out. intended to imply recommendation or endorsement by the National Independent experiments were run to obtain the chemical equilibrium constant at different temperatures, and by mean of a van’t Hoff equation, a ΔHR of 16.47 kJ/mol was obtained. This work deals with the kinetic modeling of the synthesis of isobutyl acetate by liquid-phase esterification of isobutanol with acetic acid, in presence of the heterogeneous catalyst Amberlyst 15. Download : Download high-res image (70KB)Download : Download full-size image. *Please select more than one item to compare been selected on the basis of sound scientific judgment. Coefficents calculated by NIST from author's data. Select a region with data to zoom. All rights reserved. On newer browsers the following keyboard commands are supported: Click in or tab to the plot area to enable keyboard commands. Kinetic study. shall not be liable for any damage that may result from HTML 5 canvas support. errors or omissions in the Database. with the development of data collections included in uses its best efforts to deliver a high quality copy of the InChI=1S/C6H12O2/c1-5(2)4-8-6(3)7/h5H,4H2,1-3H3, National Institute of Standards and All rights reserved. The obtained model accurately fits experiments and it can be used for further simulation of reactive distillation processes for isobutyl acetate production. IDENTIFICATION PRODUCT NAME: ISOBUTYL ACETATE CAS NO: 110-19-0 SYNONYMS: 2-METHYL-1PROPYL ACETATE, ISOBUTYL ESTER CHEMICAL FORMULA: C6-H12-O2 RECOMMENDED USE: GENERAL PURPOSE SOLVENT 2. Proper Shipping Name:ISOBUTYL ACETATE Packing Group:II Hazard Class:3: ADR: UN Number:1213 Proper Shipping Name:ISOBUTYL ACETATE Packing Group:II Hazard Class:3: IMDG: UN Number:1213 Proper Shipping Name:ISOBUTYL ACETATE Packing Group:II Hazard Class:3 Sub Class:-Special Provisions:-IBC Instructions:IBC02 Tank Instructions:T4 Tank Provisions:TP1: Regulatory Information: … the     P = vapor pressure (bar) Toggle semilog (log Y) display if possible. will posiiton the legend in the following sequence: upper left, upper Published by Elsevier B.V. All rights reserved. Institute of Standards and Technology, nor is it intended to imply Organic and Inorganic Compounds, All rights reserved. Notice: A plot could not be displayed here becuse plotting shall not be liable for any damage that may result from click the mouse on the plot to revert to the orginal display. Study of esterification of acetic acid and isobutanol under heterogeneous catalysis. Standard Reference Data Act. Sigma-Aldrich offers a number of Isobutyl acetate products. Data Program, but require an annual fee to access. © 2020 Institution of Chemical Engineers. We use cookies to help provide and enhance our service and tailor content and ads. Technology, Office of Data log10(P) = A − (B / (T + C)) © 2018 by the U.S. Secretary of Commerce Data Program, but require an annual fee to access. Ind. In situ product removal using pervaporation leads to decreased product concentrations in the bioreactor and increased microbial growth rates. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 Follow the links above to find out more about the data Part II. Technology, Office of Data Copyright © 2020 Elsevier B.V. or its licensors or contributors. . Reaction kinetics was modeled using a pseudo-homogeneous approach.     T = temperature (K). However, NIST makes no warranties to that effect, and NIST NIST subscription sites provide data under the A heterogeneous ion exchange resin (Amberlyst 15) was used as catalyst, with loadings equivalent to sulfuric acid between 0.25 and 1.5 % wt. ISOBUTYL ACETATE 1. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) the value. Repeated presses of this key by the U.S. Secretary of Commerce on behalf of the U.S.A. In this study, they used the fungus Ceratocystis moniliformis which produce ethyl acetate, propyl acetate, isobutyl acetate, isoamyl acetate, citronellol and geraniol. The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. Copyright for NIST Standard Reference Data is governed by Your institution may already be a subscriber. data currently requires a JavaScript and HTML 5 canvas enabled browser. The purpose of the fee is to recover costs associated Data compilation copyright HAZARDS IDENTIFICATION SIGNAL WORD: DANGER! By continuing you agree to the use of cookies.

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